Now showing items 1-3 of 3

    • Influence of Cs Loading on Pt/m-ZrO2 Water–Gas Shift Catalysts 

      Rajabi, Zahra; Martinelli, Michela; Watson, Caleb D.; Cronauer, Donald C.; Kropf, A. Jeremy; Jacobs, Gary (4/29/2021)
      Certain alkali metals (Na, K) at targeted loadings have been shown in recent decades to significantly promote the LT-WGS reaction. This occurs at alkali doping levels where a redshift in the C-H band of formate occurs, ...
    • Influence of Cs Promoter on Ethanol Steam-Reforming Selectivity of Pt/m-ZrO2 Catalysts at Low Temperature 

      Rajabi, Zahra; Jones, Li; Martinelli, Michela; Qian, Dali; Cronauer, Donald C.; Kropf, A. Jeremy; Watson, Caleb D.; Jacobs, Gary (9/14/2021)
      The decarboxylation pathway in ethanol steam reforming ultimately favors higher selectivity to hydrogen over the decarbonylation mechanism. The addition of an optimized amount of Cs to Pt/m-ZrO2 catalysts increases the ...
    • Na Promotion of Pt/m-ZrO2 Catalysts for the Steam Reforming of Formaldehyde 

      Martinelli, Michela; Garcia, Elijah S.; Rajabi, Zahra; Watson, Caleb D.; Kropf, A. Jeremy; Cronauer, Donald C.; Jacobs, Gary (2022-10-22)
      The decomposition selectivity of formaldehyde during steam reforming was explored using unpromoted and sodium promoted Pt/m-ZrO2 catalysts, and the Na content was varied (0.5%Na, 1%Na, 1.8%Na, 2.5%Na, and 5%Na). In situ ...