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    • Attempted Synthesis of Casbene by Intramolecular Cyclopropanation 

      Doyle, Michael; Yan, Ming (ARKIVOC;, 2002-11-14)
      The antifungal diterpene casbene has been prepared in low yield by intramolecular cyclopropanation of the vinyldiazomethane reactant formed from geranylgeraniol. Careful analysis of the reaction mixture revealed relatively ...