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Highly Efficient Olefin Isomerization Catalyzed by Metal Hydrides Derived from Dirhodium(II) Carboxylates and Catecholborane
(Main Group Metal Chemistry;, 1994-07-01)
Dirhodium(ll) tetraacetate in combination with catecholborane catalyzes the isomerization of alkenes and dienes. Effective isomerization occurs at 80-135°C with the use of only 0.1 mol % rhodium acetate. With 2-methyl-1, ...
New Catalysts and Methods for Highly Enantioselective Metal Carbene Reactions
(Pure and Applied Chemistry;, 1998-01-01)
Asymmetric catalysis of metal carbene transformations with unique chiral dirhodium(I1) carboxamidates provides highly enantioselective, diastereoselective, and regioselective syntheses of lactones and lactams via ...