Highly Efficient Olefin Isomerization Catalyzed by Metal Hydrides Derived from Dirhodium(II) Carboxylates and Catecholborane
Date
1994-07-01
Authors
Doyle, Michael
Devora, Gene
Journal Title
Journal ISSN
Volume Title
Publisher
De Gruyter Open
Abstract
Dirhodium(ll) tetraacetate in combination with catecholborane catalyzes the isomerization of alkenes and dienes. Effective isomerization occurs at 80-135°C with the use of only 0.1 mol % rhodium acetate. With 2-methyl-1,5-hexadiene the disubstituted double bond is preferentially isomerized. In addition, hydrogen transfer hydrogenation occurs with 1,4-cyclohexadienes. The mechanism of these reactions is proposed to involve organoborane addition across a Rh-0 bond which activates the catalyst for isomerization and hydrogenation.
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Citation
https://doi-org.libweb.lib.utsa.edu/10.1515/MGMC.1994.17.6.395
Department
Chemistry