Desorption and regeneration of metal oxide nanoparticles for aquatic metal removal

dc.contributor.advisorShipley, Heather J.
dc.contributor.authorHu, Jinxuan
dc.contributor.committeeMemberChen, Banglin
dc.contributor.committeeMemberHammond, Weldon W.
dc.contributor.committeeMemberJohnson, Drew
dc.contributor.committeeMemberPei, Ruoting
dc.date.accessioned2024-02-09T22:22:55Z
dc.date.available2024-02-09T22:22:55Z
dc.date.issued2012
dc.descriptionThis item is available only to currently enrolled UTSA students, faculty or staff. To download, navigate to Log In in the top right-hand corner of this screen, then select Log in with my UTSA ID.
dc.description.abstractThe adsorption-desorption of toxic compounds onto engineered nanoparticles is an important process that governs their potential as sorbents for treatment applications. In order for sorption to be cost-effective and sustainable, engineered nanoparticles need to be able to be regenerated. This study investigated the desorption of Pb (II), Cu (II), Zn (II) and Cd (II) from commercially prepared nano-Fe<sub>2</sub>O<sub>3</sub> (hematite) and nano-TiO<sub>2</sub> (anatase), along with the regeneration of nano-TiO<sub>2</sub>. Experiments were conducted using batch techniques. Desorption was evaluated for isothermal, kinetic and thermodynamic properties. Regeneration was conducted by determining the best solution for regeneration, evaluating the effects of consecutive regeneration cycles and coexisting metals, and testing the ability to treat synthetic metal polluted water. Adsorption studies showed that adsorption capacities of both nanoparticles had a trend of Pb > Zn > Cd > Cu, while nano-TiO<sub>2</sub> had larger adsorption capacities than nano-Fe<sub>2</sub>O<sub>3</sub>. Desorption of metals from both nanoparticles was pH dependent and fast; more than 98% of metals desorbed from nano-TiO<sub>2</sub> at pH 2. Metals desorption from nano-TiO2 was exothermic and non-spontaneous. Pb desorption was due to inner-sphere surface complexation while Cu and Zn showed physical interaction. pH 2 and EDTA solutions were determined to be the most effective method for regenerating nano-TiO<sub>2</sub>. Nano-TiO<sub>2</sub> was able to treat simulated metal polluted water with greater than 94% adsorption and greater than 92% desorption after 4 cycles of regeneration. This study improved the capabilities of researchers to develop practical methods for the application of nanoparticles as sorbents with simple and low-cost regeneration technologies.
dc.description.departmentCivil and Environmental Engineering
dc.format.extent171 pages
dc.format.mimetypeapplication/pdf
dc.identifier.isbn9781267615466
dc.identifier.urihttps://hdl.handle.net/20.500.12588/3844
dc.languageen
dc.subjectAdsorption
dc.subjectDesorption
dc.subjectHeavy Metal
dc.subjectNanoparticle
dc.subjectRegeneration
dc.subjectWater Treatment
dc.subject.classificationEnvironmental engineering
dc.subject.classificationEnvironmental science
dc.subject.classificationNanotechnology
dc.titleDesorption and regeneration of metal oxide nanoparticles for aquatic metal removal
dc.typeThesis
dc.type.dcmiText
dcterms.accessRightspq_closed
thesis.degree.departmentCivil and Environmental Engineering
thesis.degree.grantorUniversity of Texas at San Antonio
thesis.degree.levelDoctoral
thesis.degree.nameDoctor of Philosophy

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