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dc.contributor.authorDoyle, Michael
dc.date.accessioned2021-11-16T19:50:43Z
dc.date.available2021-11-16T19:50:43Z
dc.date.issued1998-01-01
dc.identifier.citationhttps://doi-org.libweb.lib.utsa.edu/10.1351/pac199870051123en_US
dc.identifier.issn1365-3075
dc.identifier.urihttps://hdl.handle.net/20.500.12588/725
dc.description.abstractAsymmetric catalysis of metal carbene transformations with unique chiral dirhodium(II) carboxamidates provides highly enantioselective, diastereoselective, and regioselective syntheses of lactones and lactams via cyclopropanation, cyclopropenation, carbon-hydrogen insertion, and ylide derived reactions of diazo acetates and diazoacetamides. Constructed from a dirhodium(II) core with bridging chiral pyrrolidone, oxazolidinone, azedinone, or imidazolidinone ligands, these catalysts are especially effective for intramolecular transformations. Reactions characteristically occur with high turnover numbers, and products are formed in high yield with enantiomeric excesses that are generally greater than 90%.
dc.language.isoen_USen_US
dc.publisherDe Gruyteren_US
dc.relation.ispartofseriesPure and Applied Chemistry;
dc.rightsAttribution 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/us/*
dc.titleNew Catalysts and Methods for Highly Enantioselective Metal Carbene Reactionsen_US
dc.typeArticleen_US
dc.description.departmentChemistryen_US


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Attribution 3.0 United States
Except where otherwise noted, this item's license is described as Attribution 3.0 United States