Chemoselectivity in Dirhodium(II) Catalyzed Reactions of Diazoacetoacetates Prepared from α,β-Unsaturated Ketones
| dc.contributor.author | Doyle, Michael | |
| dc.contributor.author | Zhang, Yu | |
| dc.date.accessioned | 2021-11-16T19:49:46Z | |
| dc.date.available | 2021-11-16T19:49:46Z | |
| dc.date.issued | 2010-01-01 | |
| dc.description.abstract | α-Diazo β-keto esters from zinc triflate catalyzed Mukaiyama-Michael reactions between α,β unsaturated ketones and α silyloxyvinyldiazoacetates are valuable synthons for the synthesis of compounds that can be accessed through catalytic diazo decomposition. Two sets of examples involving C-H insertion and aromatic substitution demonstrate the versatility of this methodology. | en_US |
| dc.description.department | Chemistry | en_US |
| dc.identifier.citation | Yu Zhang, & Doyle, M. P. (2010). Chemoselectivity in dirhodium(II) catalyzed reactions of diazoacetoacetates prepared from α,β-unsaturated ketones. ARKIVOC: Online Journal of Organic Chemistry, 10–16. | en_US |
| dc.identifier.issn | 1551-7012 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12588/722 | |
| dc.language.iso | en_US | en_US |
| dc.publisher | ARKAT USA | en_US |
| dc.relation.ispartofseries | ARKIVOC; | |
| dc.rights | Attribution 3.0 United States | * |
| dc.rights.uri | http://creativecommons.org/licenses/by/3.0/us/ | * |
| dc.subject | Rhodium acetate | en_US |
| dc.subject | C-H insertion | en_US |
| dc.subject | aromatic substitution | en_US |
| dc.subject | Mukaiyama-Michael reaction | en_US |
| dc.title | Chemoselectivity in Dirhodium(II) Catalyzed Reactions of Diazoacetoacetates Prepared from α,β-Unsaturated Ketones | en_US |
| dc.type | Article | en_US |