Enantioselectivity for Catalytic Cyclopropanation with Diazomalonates
Date
2003-03-24
Authors
Doyle, Michael
Hu, Wenhao
Journal Title
Journal ISSN
Volume Title
Publisher
ARKAT USA
Abstract
The use of chiral azetidinone-ligated dirhodium(II) catalysts activates dinitrogen extrusion from diazomalonates and provides access to cyclopropanation products with selectivities as high as 40-50% ee.
Description
Keywords
Cyclopropanation, diazomalonates, chiral catalysts, asymmetric synthesis
Citation
https://doi.org/10.3998/ark.5550190.0004.703
Department
Chemistry