Chemoselectivity in Dirhodium(II) Catalyzed Reactions of Diazoacetoacetates Prepared from α,β-Unsaturated Ketones
Date
2010-01-01
Authors
Doyle, Michael
Zhang, Yu
Journal Title
Journal ISSN
Volume Title
Publisher
ARKAT USA
Abstract
α-Diazo β-keto esters from zinc triflate catalyzed Mukaiyama-Michael reactions between α,β unsaturated ketones and α silyloxyvinyldiazoacetates are valuable synthons for the synthesis of compounds that can be accessed through catalytic diazo decomposition. Two sets of examples involving C-H insertion and aromatic substitution demonstrate the versatility of this methodology.
Description
Keywords
Rhodium acetate, C-H insertion, aromatic substitution, Mukaiyama-Michael reaction
Citation
Yu Zhang, & Doyle, M. P. (2010). Chemoselectivity in dirhodium(II) catalyzed reactions of diazoacetoacetates prepared from α,β-unsaturated ketones. ARKIVOC: Online Journal of Organic Chemistry, 10–16.
Department
Chemistry